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Multi-body systems
The problems with having life around double stars are many. If the stars are close, the orbits of the planets tend to become unstable because they are no longer sitting in a simple spherical gravitational well. Orbits like this would be unstable on such a timescale that the planet would not have time to form life before it was hurled out into space or sent into a non-life sustaining orbit. In addition to this, the seasons on such a planet would be extremely complicated and extremely unpleasant. You can see the differences that occur on earth simply because of an axial tilt. Imagine if you had two stars whirling around, moving back and forth with respect to the planet.
Alpha Centauri A and B are not extremely close to one another (they vary between 11 and 35 AU separation), but they are certainly close enough that any planet would feel the effects of both stars. I've done research on such systems, but I don't know offhand the stability timescale for such a system. When I get back to school, I'll try to look it up for you.
Of the two, Alpha Centauri A would be the most likely to have a life-giving planet. Other factors to consider are increased asteroid impacts due to the presence of the other star, the large x-ray flux from the corona of the Alpha Centauri B, the formation scenario (was it a capture or did they form from a single protoplanetary disk?), and planet migration. We know very little about the requirements for life, so anything I can tell you is mostly guesswork. It's possible that life takes on different forms for which the requirements are not so strict.
If we suppose that intelligent life did evolve there, there is no question that they would be able to travel to earth. We are currently able to travel to Alpha Centauri if we so choose (though the trip would probably be multi-generational and extremely expensive in terms of resources). In fact, as Richard Feynmann pointed out, if intelligent life had evolved anywhere in our galaxy in the last billion or so years, they should have reached earth by now. Make of that what you will.
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